کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
184946 | 459586 | 2014 | 8 صفحه PDF | دانلود رایگان |
• 3D network-like mesoporous NiCo2O4 nanostructures were fabricated via a solvothermal route.
• The obtained NiCo2O4 shows good electrochemical performances, especially rate capability.
• Large BET surface area and abundant mesoporosity give excellent electrochemical performances.
• This solvothermal method can be extended to prepare other binary or even ternary 3D metal oxides.
3D network-like mesoporous NiCo2O4 nanostructures have been successfully fabricated through a solvothermal route coupled with a post annealing treatment. Benefiting from its advantages of the unique 3D network-like structures with large specific surface area (170.6 m2 g−1), abundant mesoporosity (5–10 nm) and high electronic conductivity, the as-obtained NiCo2O4 manifests high specific capacitance of 931 F g−1 at 3 A g−1, remarkable capacity retention rate of 85.2 and 72.5% at 20 and 50 A g−1 compared with 2 A g−1 and superior cycling stability of 125.2% of initial capacity retention over 1000 cycles at 3 A g−1. The excellent electrochemical performances coupled with its facile and cost-effective way will render the 3D network-like mesoporous NiCo2O4 nanostructures as attractive electrode materials for promising application in supercapacitors.
Journal: Electrochimica Acta - Volume 149, 10 December 2014, Pages 144–151