کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
184995 | 459587 | 2014 | 7 صفحه PDF | دانلود رایگان |
• Hierarchical 1D ZnO nanoarchitecture is grown on a dual-dimension seeded layer.
• Carrier generation and charge transport are simultaneously maximized.
• D205 modification enhances cell power conversion efficiency up to 1.30%.
The ability to fabricate hierarchical one-dimensional (1D) ZnO nanoarchitecture with a high degree of multifunctionalities by suitable synthetic strategies still represents a vital issue towards boosting the ultimate photoelectric conversion efficiency of organic-inorganic hybrid solar cells (HSCs). We herein synthesize a hierarchical 1D ZnO nanoarchitecture i.e. ZnO NAR/NR grown on a dual-dimension seeded layer via an all-solution chemical bath deposition process. It is found that ZnO NAR/NR nanoarchitecture can accelerate electron separation and the D205 dye uptake, and hence simultaneously maximizing the key features of photoelectrode in HSCs i.e. carrier generation and charge transport. A remarkable efficiency of 1.30% is achieved under 1 sun illumination for D205-modified hierarchical ZnO HSC fabricated with a very thin layer of ZnO NAR/NR (thickness ∼1 μm) and a significant improvement is evaluated with respect to a reference photoanode made from ZnO nanorods.
ZnO nanoarchitecture was constructed on a bi-dimension seed layer via a facile chemical bath deposition method. ZnO nanoarchitecture with D205 modification as photoelectrode in organic-inorganic hybrid solar cell exhibits a high overall photoelectric conversion efficiency of ∼ 1.30% due to maximizing favorable characteristics including substantial carrier generation and efficient charge transport.Figure optionsDownload as PowerPoint slide
Journal: Electrochimica Acta - Volume 145, 1 November 2014, Pages 116–122