کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
185254 | 459592 | 2014 | 6 صفحه PDF | دانلود رایگان |

• A carbon paste electrode (CPE) was modified with a β-CD polymer.
• Tenoxicam oxidation on the CPE/poly-β-CD was adsorption controlled.
• Influence of pH, scan rate, angular velocity and concentration was evaluated.
• Fittings of i-E plots were done considering an irreversible surface reaction.
• Electrochemical evaluation of the surface inclusion constant is presented.
In this work it is shown that when a carbon paste electrode, CPE, is modified with a β-cyclodextrin polymer, the tenoxicam oxidation becomes an adsorption controlled process due to formation of a surface inclusion complex with the β-CD molecules comprising the surface of the polymer. It was found that such surface inclusion complex can be formed independently of the tenoxicam predominant species, Tenox’, in the aqueous solution namely: H2Tenox+, HTenox or Tenox−, depending on the solution pH. The electrochemical quantification of the thermodynamic constant of the equilibrium Tenox’ + β-CD (polymer) = Tenox’-β-CD (polymer) was estimated as log Kincl. = 4.26 ± 0.01. Furthermore, from the analyses of the experimental voltammograms according with Laviron's equation for an irreversible surface reaction [E. Laviron, J. Electroanal. Chem. 52 (1974) 355-393] it is shown that the surface concentration, ΓR, of tenoxicam increases as its concentration in solution does, reaching a maximum value of 1.51 × 10−10 mol cm−2 at 64 μM.
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Journal: Electrochimica Acta - Volume 140, 10 September 2014, Pages 535–540