Preparation and Characterization of MnO2/acid-treated CNT Nanocomposites for Energy Storage with Zinc Ions

The rod-like manganese dioxide (MnO2)/acid-treated carbon nanotube (a-CNT) nanocomposites have been synthesized by a simple co-precipitation method. The MnO2 nanorod with the diameter of about 10 nm and length of 50∼120 nm is in-situ deposited on the surface of acid-treated CNT through the redox reaction of KMnO4 and Mn(CH3COO)2·4H2O. Results show that the electron transfer efficiency of the MnO2/a-CNT nanocomposites is greatly enhanced and results in a high electrical conductivity. The energy storage mechanism of as-prepared MnO2/a-CNT in mild aqueous electrolyte (ZnSO4 and MnSO4) is associated with the insertion/extraction of zinc ion into/from the tunnels of crystalline α-MnO2. The composites display both excellent storage properties with zinc ions (∼400 mAh·g−1 at 1 A·g−1) and reversibility at various current rates (∼100% coulombic efficiency after 500 charge/discharge cycles). The MnO2/a-CNT nanocomposites are rather promising cathode material for high performance rechargeable zinc ion batteries.