کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
185525 | 459598 | 2014 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Mesoporous Spinel Li4Ti5O12 Nanoparticles for High Rate Lithium-ion Battery Anodes Mesoporous Spinel Li4Ti5O12 Nanoparticles for High Rate Lithium-ion Battery Anodes](/preview/png/185525.png)
• Mesoporous Li4Ti5O12 nanoparticles were prepared by a simple hydrothermal method.
• The mesoporous Li4Ti5O12 nanoparticles exhibited a diameter of 40 ± 5 nm and a pore-size distribution of 6 - 8 nm.
• Cells with the mesoporous Li4Ti5O12 anode showed excellent high rate electrochemical properties.
Mesoporous spinel lithium titanate (Li4Ti5O12) nanoparticles with the diameter of 40 ± 5 nm and the pore-size distribution of 6 - 8 nm were prepared by a simple hydrothermal method. As an anode material for lithium-ion batteries, these spinel Li4Ti5O12 mesoporous nanoparticles exhibited desirable lithium storage properties with an initial discharge capacity of 176 mAh g−1 at 1 C rate and a capacity of approximately 145 mAh g−1 after 200 cycles at a high rate of 20 C. These excellent electrochemical properties at high charge/discharge rates are due to the mesoporous nano-scale structures with small size particles, uniform mesopores and larger electrode/electrolyte contact area, which shortens the diffusion path for both electrons and Li+ ions, and offers more active sites for Li+ insertion-extraction process.
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Journal: Electrochimica Acta - Volume 133, 1 July 2014, Pages 578–582