کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
186168 | 459608 | 2014 | 7 صفحه PDF | دانلود رایگان |
• A novel design and synthesis of GO@Meso-C using GO@MOF-5 as precursor.
• GO@Meso-C hybrid material as a host material was applied for sulfur cathode.
• Electrochemical performances were improved in sulfur cathode using Go@Meso-C.
We present a design and synthesis of a hierarchical architecture of graphene oxide @ mesoporous carbon (GO@Meso-C) using graphene oxide @ metal-organic framework hybrid materials (GO@MOF-5) as both the template and precursor. Active sulfur is encapsulated into the GO@Meso-C matrix prepared via carbonize GO@MOF-5 polyhedrons for high performance lithium sulfur battery. The initial and 100th cycle discharge capacity of GO@Meso-C/S sulfur cathode are as high as 1122 mAh g−1 and 820 mAh g−1 at a current rate of 0.2 C. The remarkably high special capacity and capacity retention rate indicate that the GO@Meso-C is a promising host material for the sulfur cathode in the lithium sulfur battery applications.
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Journal: Electrochimica Acta - Volume 127, 1 May 2014, Pages 342–348