کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
186306 459610 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An investigation of the properties of conducting polymer alloys for water oxidation
ترجمه فارسی عنوان
بررسی خواص هدایت آلیاژهای پلیمری برای اکسیداسیون آب
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

This study investigates the effects of blending two conducting polymers with the aim to form an alloy photo-electrocatalyst for water oxidation. Establishing a catalyst of this nature – one that is capable of reducing the overpotential of a given electrochemical reaction through exposure to light – has the potential to aid in the development of a cost-effective water-splitting process driven by sunlight. In this work, a multi-step oxidative vapour-phase polymerisation (VPP) process was used to create a polymer mixture. This was achieved by first polymerising a layer of poly(3,4-ethylenedioxythiophene) (PEDOT) onto a substrate before placing in a chamber filled with selected monomers, namely poly(thieno[3,2-b]thiophene) (PTT) or poly(dithieno[3,2-b:2′,3′-d]thiophene) (PDTT). This allowed the monomer to polymerise with the residual oxidant within the initial PEDOT to form an interpenetrating network. Spectroscopic, electrochemical and electrical characterisation revealed a certain level of spontaneous interaction between the conducting polymer species within the mixtures, while a photo-enhanced effect of the water oxidation reaction was observed upon illumination.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 122, 10 March 2014, Pages 166–172
نویسندگان
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