کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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186638 | 459619 | 2013 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: One-step electrosynthesis of polypyrrole/graphene oxide composites for microbial fuel cell application One-step electrosynthesis of polypyrrole/graphene oxide composites for microbial fuel cell application](/preview/png/186638.png)
One-step electrosynthesis of polypyrrole (PPy)/graphene oxide (GO) composites on the graphite felt (GF) electrode was achieved by electropolymerization of pyrrole while using GO as the anionic dopant. The resulting PPy/GO composites were uniformly coated on the GF surface, with increased surface area, electronic conductivity, biocompatibility and stability as compared to PPy alone or graphene alone-modified GF electrode. The dual-chamber microbial fuel cell (MFC) equipped with the PPy/GO modified GF anode showed the maximum power density of 1326 mW m−2 (obtained from linear sweep voltammetry at a scan rate of 0.5 mV s−1), which was significantly larger than that associated with the unmodified GF anode (166 mW m−2), the electrochemically reduced GO-modified GF anode (318 mW m−2), the chemically reduced GO-modified GF anode (924 mW m−2), and the PPy-modified GF anode (1100 mW m−2). After 120 cycles of lactate feeding, the PPy/GO-GF anode exhibited good stability without noticeable performance degradation, but performance degradation was observed for the anodes modified with PPy alone or graphene alone. These results demonstrate that the PPy/GO composites, synthesized via the simple and facile electropolymerization approach, are effective anode modifying materials for improving electricity generation as well as long-term stability of MFCs.
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Journal: Electrochimica Acta - Volume 111, 30 November 2013, Pages 366–373