کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
186749 459621 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and properties of PbO2-ZrO2 nanocomposite electrodes by pulse electrodeposition
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Preparation and properties of PbO2-ZrO2 nanocomposite electrodes by pulse electrodeposition
چکیده انگلیسی

PbO2-ZrO2 nanocomposite electrodes were prepared by pulse electrodeposition in the lead nitrate plating bath containing ZrO2 nanoparticles. The effect of pulse electrodeposition parameters, such as pulse frequency, average current density and duty cycle, on the ZrO2 weight percentage in the PbO2-ZrO2 nanocomposite electrodes was investigated. The SEM and XRD tests show that PbO2-ZrO2 nanocomposite electrodes possess finer grain size than PbO2 electrodes. The service life of PbO2-ZrO2 nanocomposite electrodes reaches 298 h which is 4 times longer than that of PbO2 electrodes. The electrochemical measurements show that PbO2-ZrO2 nanocomposite electrodes possess higher oxygen evolution overpotential and larger active surface area than PbO2 electrodes. The electrocatalytic property of PbO2-ZrO2 nanocomposite electrodes was also examined for the electrochemical oxidation of rhodamine B (RhB) and good fitting was found using the relation for the pseudo-first order reaction. The bulk electrolysis shows that the PbO2-ZrO2 nanocomposite electrodes exhibit the higher RhB and COD removal efficiency than PbO2 electrodes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 117, 20 January 2014, Pages 453–459
نویسندگان
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