کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
187844 459648 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
EIS characterization of Sn|Sn(II), gluconic acid system
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
EIS characterization of Sn|Sn(II), gluconic acid system
چکیده انگلیسی

EIS and SEM techniques were applied to study processes occurring on the Sn electrode in Sn(II) gluconate solutions containing an excess of sulphate at 3 < pH < 5. Adsorption and kinetic parameters were obtained using the equivalent circuits derived for electrochemical processes involving adsorption steps.In the case of Sn(II)-free gluconate solutions, pH slightly affected impedance spectra. The most pronounced pH effect was observed for Sn(II) containing solutions: the impedance increased by 2 orders of magnitude, when pH was raised from 3 to 5. At the same time, a respective decrease in the capacitance of charged interface and in the exchange current density was detected.The revealed phenomena are interpreted in terms of formation of adsorption layer the inhibitive character of which is conditioned by species containing Sn2+ and OH− ions. The possible structure of adsorption layer is discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 85, 15 December 2012, Pages 594–599
نویسندگان
, , , , ,