کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
188565 459662 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Exploration of MnO2/carbon composites and their application to simultaneous electroanalytical determination of Pb(II) and Cd(II)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Exploration of MnO2/carbon composites and their application to simultaneous electroanalytical determination of Pb(II) and Cd(II)
چکیده انگلیسی

We report preparation of MnO2 composites with carbon (Vulcan, graphite, and carbonized nanostructured polyaniline 5-sulfosalicylate) via hydrothermal and low-temperature wet impregnation procedure. All prepared composites were characterized using thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and conductivity measurements, and their characteristics compared. Furthermore, novel micro/nanostructured manganese dioxide/carbon composite based electrodes were tested for simultaneous determination of Pb2+ and Cd2+ as model analytes by anodic stripping voltammetry. The oxidation of the targeted heavy metals at the investigated composite electrodes gave distinctive and well separated peaks with lowest detection limits of 27 nM for Pb2+ and 52 nM for Cd2+ ions obtained with hydrothermally prepared MnO2/graphite composite based electrode.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 74, 15 July 2012, Pages 158–164
نویسندگان
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