کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1887065 1043570 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pulse radiolysis study of the formation and the reactivity of baicalin radical anion, and in comparison with rutin, quercetin and acyrlate ester radical anions in ethanol
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم تشعشع
پیش نمایش صفحه اول مقاله
Pulse radiolysis study of the formation and the reactivity of baicalin radical anion, and in comparison with rutin, quercetin and acyrlate ester radical anions in ethanol
چکیده انگلیسی

The reaction of solvated electrons with baicalin in N2-saturated ethanol has been studied by pulse radiolysis. The results show that a solvated electron can add to baicalin and generate a baicalin radical anion with a maximum UV absorbance peak at 360 nm. Its molar extinction coefficient at this wavelength is 1.3×104 M−1 cm−1. The rate constant for the build-up of the baicalin radical anion is 1.3(±0.4)×1010 M−1 s−1. Decay of the radical anion is induced by a proton transfer reaction and a recombination reaction, which involves a pseudo-first-order reaction with rate constant 2.6(±0.4)×103 s−1 and a second-order reaction with rate constant 1.3(±0.2)×109 M−1 s−1. The effect of acetaldehyde on the decay of the baicalin radical anion was also investigated. Electron transfer between the baicalin radical anion and acetaldehyde was not observed, probably due to the low rate of electron transfer between the baicalin radical anion and acetaldehyde. Reactivity of the rutin, quercetin, baicalin and ethyl acrylate radical anions are also compared.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Radiation Physics and Chemistry - Volume 76, Issue 6, June 2007, Pages 951–959
نویسندگان
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