کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1887065 | 1043570 | 2007 | 9 صفحه PDF | دانلود رایگان |

The reaction of solvated electrons with baicalin in N2-saturated ethanol has been studied by pulse radiolysis. The results show that a solvated electron can add to baicalin and generate a baicalin radical anion with a maximum UV absorbance peak at 360 nm. Its molar extinction coefficient at this wavelength is 1.3×104 M−1 cm−1. The rate constant for the build-up of the baicalin radical anion is 1.3(±0.4)×1010 M−1 s−1. Decay of the radical anion is induced by a proton transfer reaction and a recombination reaction, which involves a pseudo-first-order reaction with rate constant 2.6(±0.4)×103 s−1 and a second-order reaction with rate constant 1.3(±0.2)×109 M−1 s−1. The effect of acetaldehyde on the decay of the baicalin radical anion was also investigated. Electron transfer between the baicalin radical anion and acetaldehyde was not observed, probably due to the low rate of electron transfer between the baicalin radical anion and acetaldehyde. Reactivity of the rutin, quercetin, baicalin and ethyl acrylate radical anions are also compared.
Journal: Radiation Physics and Chemistry - Volume 76, Issue 6, June 2007, Pages 951–959