کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
189127 459674 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Microwave-assisted hydrothermal synthesis of nanostructured spinel Li4Ti5O12 as anode materials for lithium ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Microwave-assisted hydrothermal synthesis of nanostructured spinel Li4Ti5O12 as anode materials for lithium ion batteries
چکیده انگلیسی

Nanoflower-like and nanoparticle spinel Li4Ti5O12 were synthesized by a microwave-assisted hydrothermal (MH) method following calcination. As-prepared Li4Ti5O12 was characterized by scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction and cyclic voltammetry. The nanoflower-like and nanoparticle Li4Ti5O12 exhibited discharge capacities of 176.7 and 109.8 mAh g−1, respectively, for the first cycle, and maintained reversible capacities of 138.4 and 91.7 mAh g−1, respectively, at a 1.1 C-rate (200 mA g−1) after 100 cycles. The better performance of nanoflower-like Li4Ti5O12 relative to nanoparticle Li4Ti5O12 is attributed to the larger specific surface area and shorter Li+ diffusion path of the former relative to the latter. The MH preparation process is straightforward and fast; thus it shows promise for widespread lithium ion battery applications.


► Microwave-assisted hydrothermal (MH) method was used for the synthesis of Li4Ti5O12.
► The synthesis process by MH method was much faster than conventional methods.
► Nanoflower-like and nanoparticle Li4Ti5O12 were synthesized.
► The effect of Li4Ti5O12 morphology on LIB performance was studied.
► Nanoflower-like Li4Ti5O12 shows better performance than the nanoparticle one.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 63, 29 February 2012, Pages 100–104
نویسندگان
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