کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
189230 | 459676 | 2011 | 6 صفحه PDF | دانلود رایگان |
A surface layer formation on positive Li1 + xMn2O4 − δ thin film model electrodes as a result of electrochemical cycling procedures has been detected and characterized by scanning electron microscopy and X-ray photoemission spectroscopy. These thin film spinel electrodes, prepared by pulsed laser deposition, were cycled in 1 M LiClO4 in propylene carbonate between 3.5 and 4.4 V vs. Li/Li+ at 40 °C and stopped at defined potentials and cycle numbers. The observed surface layers show, depending on the cycling conditions, a spotty and/or layered appearance and the fraction of this layer covering the cycled electrode depends on the charge potential and the number of electrochemical cycles.
► The spinel LiMn2O4 is a promising candidate for future battery applications.
► Good electrochemical properties of LiMn2O4 films grown on p-Si.
► Spinel thin films are used as model system to study the solid electrolyte interphase formation.
► SEI formation depends on the charge potential and the number of electrochemical cycles.
Journal: Electrochimica Acta - Volume 56, Issue 24, 1 October 2011, Pages 8539–8544