کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
189437 459679 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and electrochemiluminescence studies of tricarbonylrhenium(I) complexes with a cationic 2,2′-bipyridyl ligand
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and electrochemiluminescence studies of tricarbonylrhenium(I) complexes with a cationic 2,2′-bipyridyl ligand
چکیده انگلیسی

Two new rhenium(I) carbonyl complexes with cationic 2,2′-bipyridyl ligands were synthesized and characterized. The electrogenerated chemiluminescence (ECL) of the rhenium(I) carbonyl complexes was first investigated in aqueous solution using the co-reactant tri-n-propylamine (TPrA). The ECL behavior of the complexes was also studied in the presence of several surfactants. The oxidation of both TPrA and the rhenium(I) complexes was facilitated in the presence of Triton X-100, and the ECL intensity was enhanced 300-fold at a Au electrode.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 25, 30 October 2011, Pages 9344–9349
نویسندگان
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