کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
189555 459681 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Liquid–liquid electro-organo-synthetic processes in a carbon nanofibre membrane microreactor: Triple phase boundary effects in the absence of intentionally added electrolyte
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Liquid–liquid electro-organo-synthetic processes in a carbon nanofibre membrane microreactor: Triple phase boundary effects in the absence of intentionally added electrolyte
چکیده انگلیسی

An amphiphilic carbon nanofibre membrane electrode (ca. 50 nm fibre diameter, 50–100 μm membrane thickness) is employed as an active working electrode and separator between an aqueous electrolyte phase (with reference and counter electrode) and an immiscible organic acetonitrile phase (containing only the redox active material). Potential control is achieved with a reference and counter electrode located in the aqueous electrolyte phase, but the electrolysis is conducted in the organic acetonitrile phase in the absence of intentionally added supporting electrolyte. For the one-electron oxidation of n-butylferrocene coupled to perchlorate anion transfer from aqueous to organic phase effective electrolysis is demonstrated with an apparent mass transfer coefficient of m = 4 × 10−5 m s−1 and electrolysis of typically 1 mg n-butylferrocene in a 100 μL volume. For the two-electron reduction of tetraethyl-ethylenetetracarboxylate the apparent mass transfer coefficient m = 4 × 10−6 m s−1 is lower due to a less extended triple phase boundary reaction zone in the carbon nanofibre membrane. Nevertheless, effective electrolysis of up to 6 mg tetraethyl-ethylenetetracarboxylate in a 100 μL volume is demonstrated. Deuterated products are formed in the presence of D2O electrolyte media. The triple phase boundary dominated mechanism and future microreactor design improvements are discussed.

Figure optionsDownload as PowerPoint slideHighlights
► Amphiphilic carbon nanofiber membrane employed in electro-synthesis.
► Triple phase boundary process within a carbon membrane.
► Electrochemical deuteration in a liquid|liquid micro-reactor system.
► Triple phase boundary reaction zone effects in electro-synthesis.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 19, 30 July 2011, Pages 6764–6770
نویسندگان
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