کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
189602 | 459682 | 2011 | 6 صفحه PDF | دانلود رایگان |
Two interfacial synthesis strategies are proposed to synthesize polypyrrole samples for electrochemical capacitors (ECs). In contrast to water/organic two-phase route, unique water/ionic liquid (IL)/organic three-phase interface strategy is first performed to prepare coral-like polypyrrole with even better electrochemical capacitance, where 1-Ethyl-3-methylimidazolium tetrafluoroborate IL, as a “buffering zone”, is set between the water and organic phases to control the morphology and micro-structure of the polypyrrole phase during polymerization. The polypyrrole synthesized by three-phase interfacial route owns more ordered structure, less charge transfer resistance and better electronic conductivity, compared with two-phase method, and delivers larger specific capacitance, higher rate performance and better electrochemical stability at large current densities in 3 M KCl aqueous electrolyte.
► Interfacial synthesis strategies are proposed to synthesize PPy samples.
► Water/ionic liquid /organic three-phase interface for preparing coral-like PPy.
► Coral-like PPy with more ordered structure and better electronic conductivity.
► Coral-like PPy owns higher rate performance and better electrochemical stability.
Journal: Electrochimica Acta - Volume 56, Issue 17, 1 July 2011, Pages 6049–6054