Nano-CaCO3 templated mesoporous carbon as anode material for Li-ion batteries

Mesoporous hard carbon is obtained by pyrolyzing a mixture of sucrose and nanoscaled calcium carbonate (CaCO3) particles. The microstructure of the carbon is characterized by N2 adsorption/desorption, Hg porosimetry, field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and Raman spectroscopy. The electrochemical performances of the carbon as an anode material for lithium ion batteries are evaluated by galvanostatic charge/discharge and cyclic voltammetry tests. It is shown that this mesoporous carbon possesses high capacity, good cycling performance and rate capability, indicating the promising application of nano-CaCO3 particle as template in massive fabrication of mesoporous carbon anode materials for lithium ion batteries.

► CaCO3 nano-particle is used as a template of mesoporous carbon.
► Nano-CaCO3 template method is very simple, cheap and easy for mass production.
► The mesoporous carbon is used as anode materials for lithium ion batteries.
► The carbon possesses high capacity, good cycling performance and rate capability.