کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
189842 459686 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The yields of excited products of electrochemical reactions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The yields of excited products of electrochemical reactions
چکیده انگلیسی

The yields of triplet and singlet excitations produced by ion recombination in electrochemical reactions are studied as functions of the reaction recombination free energy. When the energy of the ion pair is rather low only the triplets appear whose primary yield monotonously grows with this energy, approaching the maximum value equal to 1 (“T-Route”). At even higher ion pair energies the triplet yield goes down and the singlet excitations become gradually the main products of the ion recombination (“S-Route”). The competition of these parallel reactions is studied at either diffusional or kinetic charge recombination and at any rate of the spin-conversion in the ion pairs.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 9, 30 March 2011, Pages 3369–3374
نویسندگان
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