کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
190171 459693 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mass changes accompanying the pseudocapacitance of hydrous RuO2 under different experimental conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Mass changes accompanying the pseudocapacitance of hydrous RuO2 under different experimental conditions
چکیده انگلیسی

Pseudocapacitance reaction of hydrous ruthenium oxide was investigated by cyclic voltammetry combined with electrochemical quartz-crystal nanobalance (EQCN) in sulfuric acid as well as in neutral solutions of Na2SO4 and K2SO4. The ruthenium oxide electrode was prepared by attaching the ruthenium oxide particles on gold covered quartz electrode. The results show that there are different types of charge taking place simultaneously during the redox reaction of ruthenium oxide electrode. Their contribution to the overall charge depends on the experimental conditions. Depending on the potential and electrolyte used the redox reaction of ruthenium oxide is accompanied either by mass loss or by mass gain. The average molar masses of the species exchanged between the solid phase and the electrolyte solution depend on the potential and scan rate. The effect of Nafion™ top layer was also investigated. It has been found that it does not affect significantly the overall specific capacitance of ruthenium oxide electrode but the apparent molar masses of exchanged species decrease in comparison with the uncovered electrodes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 10, 1 April 2011, Pages 3543–3548
نویسندگان
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