کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
190317 | 459695 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The effect of electrolyte anions incorporated into anodic oxide films on the experimental transport numbers of ions
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The effect of electrolyte anions incorporated into anodic oxide films on the experimental transport numbers of ions The effect of electrolyte anions incorporated into anodic oxide films on the experimental transport numbers of ions](/preview/png/190317.png)
چکیده انگلیسی
The growth of barrier anodic film is considered theoretically with regard to the migration of three ionic carriers: oxygen and metal ions and electrolyte anions. It is shown that the consideration of anion transport leads to the conclusion that the film grows at three interfaces: the metal/oxide and oxide/electrolyte interfaces and the interface between an oxide layer containing electrolyte anions (contaminated layer) and the oxide layer free of them (“pure” layer). The error in the measured transport numbers of metal and oxygen, which is caused by ignoring a contribution of electrolyte anions to the total charge transport, is maximum in the absence of anion motion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 11, 15 April 2011, Pages 4414–4419
Journal: Electrochimica Acta - Volume 56, Issue 11, 15 April 2011, Pages 4414–4419
نویسندگان
R.A. Mirzoev, A.D. Davydov, N.I. Stepanova,