کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
190456 | 459699 | 2010 | 6 صفحه PDF | دانلود رایگان |
The electrochemical behavior of tris(4-bromophenyl)amine (TBPA) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was comparatively studied in room temperature ionic liquids (RTILs) containing 1-butyl-3-methylimidazolium cation [BMIm]+ and the anions BF4−, PF6−and CF3SO3−. TEMPO showed a well-defined electrochemical reversibility with anodic to cathodic peak current ratio (Ia/Ic) equals to unity in all RTILs, at a glassy carbon electrode. In contrast, Ia/Ic ratio greater than unity was observed at all scan rates employed (10–1000 mV s−1) in cyclic voltammograms (CV) of TBPA in RTILs. Controlled-potential bulk electrolysis of TBPA in RTILs yielded a dark blue colored solution of monocation TBPA+, which is stable under nitrogen. Diffusion coefficient of TBPA+ cation was determined in all three ILs by chronoamperometry and found to be at least one order of magnitude less than the calculated value of TBPA. This effect, in conjunction with the deviation of the Ia/Ic ratio from unity could be ascribed to ion-pairing interaction between the TBPA+ cation and the anion of the RTILs.
Journal: Electrochimica Acta - Volume 55, Issue 27, 30 November 2010, Pages 8319–8324