کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
190559 459701 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The preparation of poly(glycidyl acrylate)–polypyrrole gel-electrolyte and its application in dye-sensitized solar cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The preparation of poly(glycidyl acrylate)–polypyrrole gel-electrolyte and its application in dye-sensitized solar cells
چکیده انگلیسی

A microporous hybrid of poly(glycidyl acrylate)–polypyrrole (PGA–PPy) was synthesized by a two-step solution polymerization. Using this hybrid as polymer host, a gel-electrolyte with high conductivity of 12.83 mS cm−1 was prepared. The researches by scanning electron microscopy (SEM), Fourier transform infrared spectra (FTIR), and cyclic voltammetry (CV) show that the microporous structure and functional groups for PGA allows the higher absorbency and good ionic salt tolerance for the electrolyte, the introduction of PPy causes a lower charge-transfer resistance and higher electrocatalytic activity for the I3−/I− redox reaction for the electrolyte. Based on the electrolyte, a dye-sensitized solar cell with a light-to-electrical energy conversion efficiency of 5.03% is achieved, under illumination with a simulated solar light of 100 mW cm−2 (AM 1.5).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 17, 1 July 2010, Pages 4883–4888
نویسندگان
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