کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
190904 459709 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Aluminum assisted electrodeposition of europium in LiCl–KCl molten salt
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Aluminum assisted electrodeposition of europium in LiCl–KCl molten salt
چکیده انگلیسی

Cyclic voltammetry (CV), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) were employed to investigate the electrodeposition of Eu and Al in an LiCl–KCl eutectic melt containing Eu2+ and Al3+ at 450 °C. In order to deposit a pure Eu and Al alloy, the stoichiometrically lower concentration of Al3+ than that of Eu2+ and Al wires as a counter electrode was introduced into the bath of LiCl–KCl melt for the electrodeposition. The electrodeposition takes place at a potential more negative than −1.95 V vs. Ag|Ag+ while the deposit is oxidized at more positive potential than −1.92 V. Two new reduction peaks and an anodic peak on a W working electrode were observed at −2.39 V, −2.42 V, and −2.1 V, vs. Ag|Ag+, respectively, suggesting that the potential window of the Al system in LiCl–KCl melt can be extended to −2.43 V vs. Ag|Ag+. The EDS analysis indicated that AlEu can be deposited at the potential more negative than −2.37 V.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 8, 1 March 2010, Pages 3022–3025
نویسندگان
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