کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
191342 | 459720 | 2010 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Enhanced electrochemical treatment of phenolic pollutants by an effective adsorption and release process Enhanced electrochemical treatment of phenolic pollutants by an effective adsorption and release process](/preview/png/191342.png)
Phenolic compounds are the most prevalent pollutants in industrial wastewater. Here we report on a novel approach: using adsorption and release process to improve the efficiency of electrochemical oxidation of phenolic pollutants. To illustrate this innovative technique, three phenolic compounds, phenol, p-nitrophenol (p-NPh) and p-cresol, were selected as model pollutants. The adsorption studies were carried out by adsorbing the three pollutants onto a hyper-cross-linked resin (Purolite Macronet MN-200). The adsorption isotherms, adsorption kinetics and the effect of temperature on adsorption were systematically investigated. Our experimental results have shown that the MN-200 resin exhibits a high removal efficiency of the three model pollutants and the adsorbed phenolic compounds can be efficiently released in a NaOH solution. The preconcentrated phenolic compounds were further treated using electrochemical oxidation at the Ti/SnO2–Sb2O5–IrO2 electrode. The first-order model fits the kinetics data of the electrochemical oxidation very well, showing that the degradation rate constant decreases in the order of p-NPh > phenol > p-cresol. Our study has demonstrated that the integration of the effective preconcentration process and the advanced electrochemical oxidation offers a promising approach for the efficient elimination of phenolic pollutants in wastewater.
Journal: Electrochimica Acta - Volume 55, Issue 19, 30 July 2010, Pages 5367–5374