کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
191817 459729 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study on synthesis and electrochemical properties of novel ferrocene-based compounds and their applications in anion recognition
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Study on synthesis and electrochemical properties of novel ferrocene-based compounds and their applications in anion recognition
چکیده انگلیسی

Two novel ferrocene-based compounds glycidyl ester of ferrocene carboxylate (GEFC) and 1,3-diferrocenecarboxylic acid diacylglycerol (DFCDG) were synthesized and characterized by 1H NMR and mass spectrum. The influence of some factors, namely, solvent type, potential scan rate, electrolyte concentration and [Fe] unit concentration, on the electrochemical behaviors of two novel ferrocene-based compounds was investigated, and the mechanism of the electrode processes was studied. Finally, two compounds were applied to sense the H2PO4− by cyclic voltammetry (CV) method and it was found that the DFCDG with a symmetric structure which was synthesized through ring opening reaction of ferrocene carboxylate and GEFC showed stronger interaction with the H2PO4− than GEFC.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 23, 30 September 2009, Pages 5413–5420
نویسندگان
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