کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
192065 459735 2010 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new modified electrode based on electrochemical oxidation of 1-amino-5,6,7,8-tetrahydronaphthalene in acetonitrile
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A new modified electrode based on electrochemical oxidation of 1-amino-5,6,7,8-tetrahydronaphthalene in acetonitrile
چکیده انگلیسی

Electrooxidative polymerization of the 1-amino-5,6,7,8-tetrahydronaphthalene (ATHN) monomer on a glassy carbon (GC) electrode was carried out in an acetonitrile solution containing LiClO4 using consecutive multisweep cyclic voltammetry and controlled potential electrolysis techniques. The factors that affected the film formation, such as monomer concentration, number of sweeping cycles, sweep rate and limits of potential cycling were investigated in detail. The obtained modified electrode was active only in acidic solutions, and its activity was found to be pH dependent. The effects of pH and temperature on the obtained modified electrode were studied. The obtained modified electrode has been found to improve the electrochemical reversibility and decrease the overpotential of hydroquinone.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 5, 1 February 2010, Pages 1509–1518
نویسندگان
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