کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192170 | 459736 | 2009 | 8 صفحه PDF | دانلود رایگان |

MWCNT-PSS/PEDOT/MnO2 nano-composite electrodes were fabricated by generating pseudo-capacitive poly(3,4-ethylenedioxythiophene) (PEDOT)/MnO2 nano-structures on poly(styrene sulfonate) (PSS) dispersed multiwalled carbon nanotubes (MWCNTs). PSS dispersed MWCNTs (MWCNT-PSS) facilitated the growth of PEDOT and MnO2 into nano-rods with large active surface area and good electrical conductivity. The ternary MWCNT-PSS/PEDOT/MnO2 nano-composite electrode was studied for the application in super-capacitors, and exhibited excellent capacitive behavior between −0.2 V and 0.8 V (vs. saturated Ag/AgCl electrode) with high reversibility. Specific capacitance of the nano-composite electrode was found as high as 375 F g−1. In contrast, specific capacitance of MWCNT-PSS/MnO2 and MWCNT-PSS nano-composite electrodes is 175 F g−1 and 15 F g−1, respectively. Based on cyclic voltammetric studies and cycle-life tests, the MWCNT-PSS/PEDOT/MnO2 nano-composite electrode gave a highly stable and reversible performance up to 2000 cycles. Our studies demonstrate that the synergistic combination of MWCNT-PSS, PEDOT and MnO2 has advantages over the sum of the individual components.
Journal: Electrochimica Acta - Volume 54, Issue 27, 30 November 2009, Pages 7148–7155