کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192535 | 459744 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical studies of osmium-(pyrrole-methyl) pyridine-co-polymers deposited using the membrane template method
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrochemical studies of osmium-(pyrrole-methyl) pyridine-co-polymers deposited using the membrane template method Electrochemical studies of osmium-(pyrrole-methyl) pyridine-co-polymers deposited using the membrane template method](/preview/png/192535.png)
چکیده انگلیسی
The electrochemical characterisation of films formed by co-polymerisation of [Os(2,2′-bipyridine)2XCl] (Os–PMP) where X is 3-(pyrrole-1yl-methyl)pyridine with 3-methyl thiophene or 1,2-diaminobenzene was carried out. The use of the membrane template method, which allowed growth of tubules of redox co-polymer was employed in the case of 1,2-diaminobenzene. Cyclic voltammetry allowed formation of the most stable 3-methylthiophene/Os–PMP films while chronocoulometry was used to co-polymerise Os–PMP with 1,2-diaminobenzene, resulting in stable films of co-polymer micro-tubules with thin-film behaviour up to 0.5 V s−1 (r2 = 0.9997). Surface analysis was carried out using SEM.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 53, Issue 13, 20 May 2008, Pages 4550–4556
Journal: Electrochimica Acta - Volume 53, Issue 13, 20 May 2008, Pages 4550–4556
نویسندگان
Susan Warren, Rodica Doaga, Timothy McCormac, Eithne Dempsey,