کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192558 | 459745 | 2009 | 8 صفحه PDF | دانلود رایگان |
Rhenium–nickel alloys were deposited on copper substrates in a small three-electrode cell, under galvanostatic conditions. The bath solution consisted of ammonium perrhenate, citric acid and nickel sulfamate. The effects of bath composition and deposition time were studied. The Faradaic efficiency (FE) and partial deposition current densities were calculated based on mass gain and elemental analysis using energy dispersive spectroscopy. The surface morphology was characterized by scanning electron microscopy. The thickness of the coating was measured on metallographic cross-sections. The results are discussed with emphasis on routes to increase the Faradaic efficiency and rhenium content in the coating. A plausible mechanism for the electrodeposition of rhenium–nickel alloys is presented.
Journal: Electrochimica Acta - Volume 54, Issue 25, 30 October 2009, Pages 6028–6035