کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
192752 459750 2009 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A computational multi-reaction model of a Cu electrolysis cell
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A computational multi-reaction model of a Cu electrolysis cell
چکیده انگلیسی

A computational model for quantitatively describing the behavior of four simultaneous chemical reactions taking place on two copper electrodes in a Cu–Cu electrolysis cell is formulated. The individual reaction rates, corresponding current densities and total cell current and voltage are obtained as direct model output. The model parameters are found based on cyclic voltammetry experiments done in a Cu–Cu electrolysis cell with CuSO4 (aq) concentrations between 0.1 M and 1 M. The model is fit against the data of one experiment and compared against a series of other measurements. A full set of model parameters is given and the effect of selected parameters on the simulated current–time response is analyzed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 24, 1 October 2009, Pages 5949–5958
نویسندگان
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