کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
192753 459750 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Anodic acyloxylation based on the acid–base reactions between acetic acid or trifluoroacetic acid and solid-supported bases
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Anodic acyloxylation based on the acid–base reactions between acetic acid or trifluoroacetic acid and solid-supported bases
چکیده انگلیسی

We have developed a novel electrolytic system for anodic acyloxylation based on the acid–base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 24, 1 October 2009, Pages 5959–5963
نویسندگان
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