کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
193096 459761 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
In situ atomic force microscopy investigation of copper behaviour and polypyrrole deposition from salicylate medium
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
In situ atomic force microscopy investigation of copper behaviour and polypyrrole deposition from salicylate medium
چکیده انگلیسی

The morphological modifications accompanying the electrochemical behaviour of copper in aqueous salicylate solution, have been investigated by in situ atomic force microscopy (AFM), with the purpose of elucidating the role of salicylate ions during polypyrrole electrodeposition onto this oxidisable metal.The surface changes revealed by in situ AFM images, are in agreement with previous attributed electrochemical processes, namely the formation of a non-uniform passivating layer, which does not completely block the copper surface. The presence of such layer prevents a strong anodic copper dissolution without hinder the pyrrrole oxidation. Pyrrole electropolymerization process has been also followed in real-time by AFM, and occurs through the formation of a first polymer layer, which follows the initial copper surfaces irregularities and is characterized by polypyrrole round nodules of different sizes, whereas for thick polymer films the influence of substrate defects is not detected.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 53, Issue 19, 1 August 2008, Pages 5783–5788
نویسندگان
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