کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
194379 | 459790 | 2008 | 6 صفحه PDF | دانلود رایگان |
In this work, carbon-coated lithium-ion intercalated compound LiTi2(PO4)3 and MnO2 have been synthesized and they deliver a capacity of 90 and 60 mAh/g in 1 M Li2SO4 neutral aqueous electrolyte within safe potentials without O2 and H2 evolution, respectively. The novel hybrid supercapacitor in which MnO2 was used as a positive electrode and carbon-coated LiTi2(PO4)3 as a negative electrode was assembled and the LiTi2(PO4)3/MnO2 hybrid supercapacitor showed a sloping voltage profile from 0.7 to 1.9 V, at an average voltage near 1.3 V, and delivers a capacity of 36 mAh/g and an energy density of 47 Wh/kg based on the total weight of the active electrode materials. It exhibits a desirable profile and maintains over 80% of its initial energy density after 1000 cycles. The hybrid supercapacitor also exhibit an excellent rate capability, even at a power density of 1000 W/kg, it has a specific energy 25 Wh/kg compared with 43 Wh/kg at the power density about 200 W/kg.
Journal: Electrochimica Acta - Volume 53, Issue 28, 30 November 2008, Pages 8128–8133