Further to the “Reply to remarks on Discussion of three models used for the investigation of insertion/extraction processes by the potential step chronoamperometry technique [C. Montella, Electrochim. Acta 50 (2005) 3746] by H.-C. Shin, S.-I. Pyun, K.-N.

Some issues have been critically discussed regarding the cell-impedance-controlled model inspired by the recent publication entitled “Reply to remarks on Discussion of three models used for the investigation of insertion/extraction processes by the potential step chronoamperometry technique [C. Montella, Electrochim. Acta 50 (2005) 3746] by H.-C. Shin, S.-I. Pyun, K.-N. Jung” [Electrochim. Acta 51 (2006) 2775]. In particular, two points on the definition of the internal cell resistance and the intersection phenomenon of chronoamperometric curves (CAs) have been revisited on the basis of the combination of experimental and theoretical approaches.