کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
195154 459808 2006 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical and theoretical investigation on the reaction of transition metals with Li3N
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemical and theoretical investigation on the reaction of transition metals with Li3N
چکیده انگلیسی

The electrochemical reactivity of Li3N with transition metals (M = Mn, Fe, Co, Ni) is examined by discharge/charge, cyclic voltammetry, X-ray diffraction and X-ray photoelectron spectroscopy measurements. An attempt is made to understand this reversible electrochemical reaction of transition metals with Li3N from the chemical reactions point of view. Density functional theoretical calculation results suggest that a stable complex MNLi3 could be formed by the insertion of transition metal in Li3N with exothermic as an intermediate, subsequent the decomposition process of these insertion compounds should make a main contribution to release Li.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 23, 15 June 2006, Pages 4802–4814
نویسندگان
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