کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
195154 | 459808 | 2006 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical and theoretical investigation on the reaction of transition metals with Li3N
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The electrochemical reactivity of Li3N with transition metals (M = Mn, Fe, Co, Ni) is examined by discharge/charge, cyclic voltammetry, X-ray diffraction and X-ray photoelectron spectroscopy measurements. An attempt is made to understand this reversible electrochemical reaction of transition metals with Li3N from the chemical reactions point of view. Density functional theoretical calculation results suggest that a stable complex MNLi3 could be formed by the insertion of transition metal in Li3N with exothermic as an intermediate, subsequent the decomposition process of these insertion compounds should make a main contribution to release Li.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 23, 15 June 2006, Pages 4802–4814
Journal: Electrochimica Acta - Volume 51, Issue 23, 15 June 2006, Pages 4802–4814
نویسندگان
Jun Ma, Le Yu, Zheng-Wen Fu,