کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
195685 459819 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Covalent and embedment immobilization of macrocyclic polyamines on gold electrodes and their voltammetric responses towards ethene dicarboxylic acids
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Covalent and embedment immobilization of macrocyclic polyamines on gold electrodes and their voltammetric responses towards ethene dicarboxylic acids
چکیده انگلیسی

In the paper presented, we report on the electrochemical signals generated upon interaction between polyamine host molecules immobilized on the surface of gold electrodes and anions of ethene dicarboxylic acids existing in the aqueous phase.Two methods of gold electrode modification will be compared: covalent (macrocyclic polyamine molecules with –SH groups were bound directly on the gold surface) and embedment (polyamines with long alkyl chains were adsorbed into the monolayer of 1-dodecanethiol deposited on the gold surface).The signals generated due to formation of supramolecular complexes between macrocyclic polyamines and anions of cis- and trans-isomers of ethene dicarboxylic acids at the electrode interface were measured by cyclic voltammetry and Osteryoung square-wave voltammetry with [Ru(NH3)6]3+ as an electroactive marker.The selectivity and sensitivity of the presented sensors were compared with those ion selective electrodes (ISEs) incorporated with the same and similar macrocyclic polyamines.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 11, 15 February 2006, Pages 2289–2297
نویسندگان
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