کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
195768 | 459821 | 2007 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Interactions among metastable pits on heterogeneous electrodes Interactions among metastable pits on heterogeneous electrodes](/preview/png/195768.png)
A previously developed spatiotemporal model of the interactions among metastable pits on homogeneous electrodes is extended to heterogeneous surfaces with randomly distributed inclusion sites in an otherwise passive electrode. The inclusions are treated as favored sites for pit initiation events. The effect of the spatial density of inclusions on susceptibility to explosive growth in pitting corrosion is investigated. It is shown that there exist critical values of the pit density for the explosive growth of metastable pits that leads to a transition to pitting corrosion. Convective mass transport is shown to alter the density required for explosive growth. The effect of a limitation on the number of times that an inclusion can initiate a pit on the transition to the pitting corrosion is also considered.
Journal: Electrochimica Acta - Volume 52, Issue 24, 1 August 2007, Pages 6784–6792