کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
195940 459827 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sol–gel derived carbon ceramic electrode for the investigation of the electrochemical behavior and electrocatalytic activity of neodymium hexacyanoferrate
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Sol–gel derived carbon ceramic electrode for the investigation of the electrochemical behavior and electrocatalytic activity of neodymium hexacyanoferrate
چکیده انگلیسی

The electrochemical properties of an electroactive rare earth metal hexacyanoferrate, neodymium hexacyanoferrate (NdHCF) were studied by mechanically attaching NdHCF samples to the surface of carbon ceramic electrodes (CCEs) derived from sol–gel technique. The resulting modified electrodes exhibit well-defined redox responses with the formal potential of 0.241 V (versus SCE) at a scan rate of 20 mV s−1 in 0.5 M KCl solution. The voltammetric characteristics of the NdHCF-modified CCEs in the presence of different alkali metal cations (Li+, Na+, K+, Rb+ and Cs+) were investigated by voltammetry. The NdHCF-modified CCEs presented a good electrocatalytic activity towards the reduction of hydrogen peroxide (H2O2), and was used for amperometric detection of H2O2. In addition, the NdHCF-CCEs exhibited a distinct advantage of simple preparation, surface renewal, good stability and reproducibility.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 52, Issue 13, 20 March 2007, Pages 4506–4512
نویسندگان
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