کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
195942 | 459827 | 2007 | 7 صفحه PDF | دانلود رایگان |
Highly crystalline spinel LiMn2O4 was successfully synthesized by annealing lithiated MnO2 at a relative low temperature of 600 °C, in which the lithiated MnO2 was prepared by chemical lithiation of the electrolytic manganese dioxide (EMD) and LiI. The LiI/MnO2 ratio and the annealing temperature were optimized to obtain the pure phase LiMn2O4. With the LiI/MnO2 molar ratio of 0.75, and annealing temperature of 600 °C, the resulting compounds showed a high initial discharge capacity of 127 mAh g−1 at a current rate of 40 mAh g−1. Moreover, it exhibited excellent cycling and high rate capability, maintaining 90% of its initial capacity after 100 charge–discharge cycles, at a discharge rate of 5 C, it kept more than 85% of the reversible capacity compared with that of 0.1 C.
Journal: Electrochimica Acta - Volume 52, Issue 13, 20 March 2007, Pages 4525–4531