کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
196038 | 459831 | 2007 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Life of the Tafel equation: Current understanding and prospects for the second century
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
The life of Tafel equation is considered briefly as evolution in the understanding of Tafel's empiric parameters in the framework of various phenomenological and theoretical approaches. Modern theories of the interfacial charge transfer reactions are employed to explain the behavior of transfer coefficient versus electrode overvoltage and deviations of this quantity from 0.5 at low overvoltage. The effects of intramolecular reorganization, orbital overlap, reactant quantum modes and solvent dynamics are addressed and illustrated by model calculations. An attempt is made to propose new explanations of some data reported in the literature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 52, Issue 11, 1 March 2007, Pages 3493–3504
Journal: Electrochimica Acta - Volume 52, Issue 11, 1 March 2007, Pages 3493–3504
نویسندگان
Oleg A. Petrii, Renat R. Nazmutdinov, Michael D. Bronshtein, Galina A. Tsirlina,