کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
196448 459841 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Membraneless laminar flow-based micro fuel cells operating in alkaline, acidic, and acidic/alkaline media
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Membraneless laminar flow-based micro fuel cells operating in alkaline, acidic, and acidic/alkaline media
چکیده انگلیسی

The lack of a polymer electrolyte membrane (PEM, e.g. Nafion) in membraneless, laminar flow-based micro fuel cells (LF-FCs) eliminates several PEM-related issues such as fuel crossover, cathode flooding, and anode dry-out, as we reported previously. This paper explores the media flexibility of LF-FCs by working in acidic and alkaline media, as well under “mixed-media” conditions in which the anode is in acidic media while the cathode is in alkali, or vice versa. Operating a fuel cell under alkaline conditions has positive effects on the reaction kinetics, both at the anode and cathode, while the cell performance under “mixed-media” conditions offers an opportunity to increase the maximum achievable open cell potential (OCP). The lack of media-related constraints and the simplicity of the LF-FC design allow for these experiments to be performed consecutively in a single LF-FC without changing the system, except for altering the composition/pH of the fuel and oxidant stream. The performance of LF-FCs operated with different media is described and compared.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 50, Issue 27, 20 September 2005, Pages 5390–5398
نویسندگان
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