کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
196647 459848 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cycling-induced degradation of LiCoO2 thin-film cathodes at elevated temperature
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Cycling-induced degradation of LiCoO2 thin-film cathodes at elevated temperature
چکیده انگلیسی

The cycle life of LiCoO2-based all solid-state thin-film cells has been studied at room temperature, and at elevated temperatures of 50, 100, and 150 °C. X-ray diffraction, as well as Raman analysis, has been used to complement the electrochemical data in examining structural and chemical changes. XRD and Raman spectroscopy data indicate that elevated temperature soaks of the thin-film batteries in the quiescent state causes no discernable changes in the LiCoO2 cathode layer. However, when the thin-film batteries are cycled at elevated temperatures, decreases in average grain size of the LiCoO2 film occur with dramatic concomitant charge and discharge capacity loss.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 15, 1 April 2006, Pages 3001–3007
نویسندگان
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