کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
196766 459852 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Grain dependent electrochemical investigations on pure iron in acetate buffer pH 6.0
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Grain dependent electrochemical investigations on pure iron in acetate buffer pH 6.0
چکیده انگلیسی

The influence of grain orientation on the electrochemical behaviour of iron in acetate buffer pH 6.0 was analyzed using a capillary microcell. Cyclic voltammetry and simultaneous capacity measurements were performed on the two crystal faces of an iron (1 0 0)/(1 1 1) bi-crystal, on the grain boundary between these two orientations and on several single grains of a coarse grain iron sample. The combination with electron back scattered diffraction (EBSD) yields the surface orientation of the analyzed grains and makes it possible to perform orientation dependent experiments on the polycrystalline metal. Clear differences in the electrochemical behaviour, e.g. in corrosion tendency and oxide formation rate were found between the orientations (1 0 0) and (1 1 1) of the iron bi-crystal and between several grain orientations of the polycrystalline sample.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 13, 5 March 2006, Pages 2625–2630
نویسندگان
, , , , ,