کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
197373 | 459883 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ionic conductivities of hybrid inorganic sulfide–polyether electrolytes
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Ionic conductivities of hybrid inorganic sulfide–polyether electrolytes Ionic conductivities of hybrid inorganic sulfide–polyether electrolytes](/preview/png/197373.png)
چکیده انگلیسی
Hybrid polymers combining P2S5 moieties with oligoether spacers have been prepared, and the conductivities and glass transition temperatures of their solutions of lithium salts have been examined. The materials are highly viscous but mostly not rubbery. A high ambient temperature conductivity of 10−3.9 S cm−1 was obtained with LiTFSI dissolved in the sulfide–PEO matrix. The decoupling of Li+ motion from the polymer segmental motion is demonstrated, suggesting that, in certain cases, the transport number for Li+ ion in the sulfide–PEO matrix will be much higher than in a typical PEO-based salt-in-polymer system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 48, Issues 14–16, 30 June 2003, Pages 2003–2008
Journal: Electrochimica Acta - Volume 48, Issues 14–16, 30 June 2003, Pages 2003–2008
نویسندگان
Akitoshi Hayashi, Limin Wang, C.Austen Angell,