|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|200940||460525||2016||7 صفحه PDF||سفارش دهید||دانلود رایگان|
In this paper the ability of the UNIFAC methods (original UNIFAC and modified UNIFAC (Dortmund)) to predict the excess molar enthalpies, HE, is considered. The predicted and the obtained earlier experimental values of the excess molar enthalpies for 5 binary systems of n-propanol, acetic acid, n-propyl acetate, and water were compared. Since the both methods represent the HE unsatisfactorily, new set of group interaction parameters of the UNIFAC (Dortmund) method for mentioned above compounds was evaluated.
Journal: Fluid Phase Equilibria - Volume 427, 15 November 2016, Pages 202–208