کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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202486 | 460605 | 2013 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Experimental determination and theoretical modeling of the vapor–liquid equilibrium and densities of the binary system butan-2-ol + tetrahydro-2H-pyran Experimental determination and theoretical modeling of the vapor–liquid equilibrium and densities of the binary system butan-2-ol + tetrahydro-2H-pyran](/preview/png/202486.png)
Isobaric vapor–liquid equilibrium (VLE) data have been measured for the binary system butan-2-ol + tetrahydro-2H-pyran at 50, 75, and 94 kPa and over the temperature range from 339 to 370 K using a vapor–liquid equilibrium still with circulation of both phases. Mixing volumes were also determined at 298.15 K and atmospheric pressure with a vibrating tube densimeter. According to experimental results, the zeotropic mixture exhibits slight positive deviation from ideal behavior over the experimental range. The excess molar volumes (v˜E) of the system are positive over the whole mole fraction range. The VLE data of the binary mixture satisfy the Fredenlund's consistency test and were well-correlated by the Wohl, nonrandom two-liquid (NRTL), Wilson, and universal quasichemical (UNIQUAC) equations for all of the measured isobars. The v˜E, in turn, were satisfactorily correlated using a second order Redlich–Kister equation.The theoretical modeling of the measured VLE and v˜E data has been carried out using the polar perturbed chain statistical association fluid theory (PPC-SAFT) equation of state. In this molecular based approach, butan-2-ol was described as a polar auto-associating molecule, while tetrahydro-2H-pyran is treated as polar molecule. Molecular interactions between these two components have been approximated in terms of a hetero-association theory. It is demonstrated that a common set of parameters is able to simultaneously reproduce with good agreement both phase equilibrium and excess molar volumes measurements.
Journal: Fluid Phase Equilibria - Volume 342, 25 March 2013, Pages 52–59