کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
202797 460622 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid–liquid phase equilibria in the systems K2SO4–MSO4–H2O (M = Co, Ni, Cu) from ambient to enhanced temperatures
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Solid–liquid phase equilibria in the systems K2SO4–MSO4–H2O (M = Co, Ni, Cu) from ambient to enhanced temperatures
چکیده انگلیسی

Reviewing the literature solubility isotherms in the ternary systems K2SO4–MSO4–H2O (M = Co, Ni, Cu, Zn) revealed a lack at ambient temperatures. The solid–liquid phase equilibria have been determined in the systems K2SO4–MSO4–H2O (M = Co, Ni, Cu) at T = 313 K. With increasing bivalent metal sulfate concentration, the solubility of potassium sulfate rises until the two-salt point is reached. Reciprocally, the solubility of the bivalent metal sulfate hydrates (CoSO4·7H2O, α-NiSO4·6H2O, CuSO4·5H2O) increases with rising potassium sulfate concentration. In all three systems the double salts of Tutton's type K2SO4·MSO4·6H2O (M = Co, Ni, Cu) are formed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 291, Issue 2, 15 May 2010, Pages 154–158
نویسندگان
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