کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
202889 460626 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogen separation via forming hydrate in W/O emulsion
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Hydrogen separation via forming hydrate in W/O emulsion
چکیده انگلیسی

In this work, hydrogen was separated from CH4/H2 gas mixtures via forming hydrate in water in oil emulsion. Aqueous phase is the aqueous solution of 3.0 wt% Span 20. Oil phase is the mixture of diesel and cyclopentane (CP) with a CP concentration of 50 vol%. Span 20 was used to disperse water or hydrate in diesel to form emulsion or hydrate slurry. CP was used to moderate the hydrate formation condition. Two H2/CH4 feed gas mixtures, containing 68.0 mol% and 84.7 mol% of hydrogen respectively, were prepared. A series of experiments were performed with respect to two feed gas mixtures to investigate the influences of temperature, pressure, and water cut upon the separation efficiency. Our experimental results show that suitable low temperature (274.15 K or so), high pressure (5–6 MPa), and water cut around 20 vol% are favorable for H2 separation. The highest separation factor of H2/CH4 reaches 49. After a two-stage separation at 274.15 K, the concentration of H2 in gas phase could be increased from 68 mol% to more than 92 mol% and nearly 90% of H2 can be recovered in gas phase.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 362, 25 January 2014, Pages 252–257
نویسندگان
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