کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
203923 460686 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new coordination number model and heat capacity of square-well fluids of variable width
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A new coordination number model and heat capacity of square-well fluids of variable width
چکیده انگلیسی

A new coordination number model for square-well fluid is proposed in this work. The model modifies the theory previously developed for the coordination number of square-well fluids derived on the basis of the generalized van der Waals theory by Largo and Solana. In the present work, we have calculated the co-ordination number of a square-well fluid on the basis of high temperature expansion (HTE) approach along with the modified formula of the maximum reduced density and a novel approach to derive the coordination number of hard sphere fluids.We have also performed the theoretical predictions of constant-volume excess heat capacity of the square-well fluids. It is shown that the theoretical predictions of the constant-volume excess heat capacity determined by second-order perturbation term are in much better agreement with simulation data than to the values of CVE/NK obtained by other workers due to the better description of the second-order term.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 243, Issues 1–2, 10 May 2006, Pages 101–106
نویسندگان
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